A NEW SUPRAMOLECULAR MACROCYCLIC HOST INCORPORATED WITH RUTHENOCENE IONOSPHERE-SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF '-TRIS(RUTHENOCENYLMETHYL)-1,4,7-TRIAZACYCLONONANE PERCHLORATE

Authors
YIN YG CHEUNG KK WONG WT
Citation
Yg. Yin et al., A NEW SUPRAMOLECULAR MACROCYCLIC HOST INCORPORATED WITH RUTHENOCENE IONOSPHERE-SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF '-TRIS(RUTHENOCENYLMETHYL)-1,4,7-TRIAZACYCLONONANE PERCHLORATE, Polyhedron, 16(16), 1997, pp. 2889-2891
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
16
Issue
16
Year of publication
1997
Pages
2889 - 2891
Database
ISI
SICI code
0277-5387(1997)16:16<2889:ANSMHI>2.0.ZU;2-A
Abstract
The supramolecular host molecule '-tris(ruthenocenylmethyl)-1,4,7-tria zacyclononane perchlorate [LH] ClO4 was prepared and its molecular str ucture was determined by single crystal X-ray analysis. The guest prot on was localized on one of the aza atoms of the macrocycle (N-H : 0.71 Angstrom). Cyclic voltammetric measurement displays an irreversible o xidation wave at 0.84 V and is attributable to the oxidation of Ru-II to Ru-III of the appended metallocenes. (C) 1997 Elsevier Science Ltd.