The synthesis of binuclear half-open 1,1 '-biferrocene: redox behavior andan interpretation of the Fe-57 Mossbauer data

Authors
Dong, TY Chang, CK Cheng, CH
Citation
Ty. Dong et al., The synthesis of binuclear half-open 1,1 '-biferrocene: redox behavior andan interpretation of the Fe-57 Mossbauer data, J ORGMET CH, 587(1), 1999, pp. 46-48
Citations number
16
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
587
Issue
1
Year of publication
1999
Pages
46 - 48
Database
ISI
SICI code
0022-328X(19990915)587:1<46:TSOBH1>2.0.ZU;2-U
Abstract
Replacing the two Cp rings of 1,1'-biferrocene With pentadienyl ligands res ults in a cathodic shift of the redox potential for the ferrocene/ferroceni um couple and decreased quadrupole splitting in the Mossbauer spectrum and these findings can be accounted for by a change in the orbital population a round the metal atom, (C) 1999 Elsevier Science S.A. All rights reserved.