In recent years natural biosurfactants have attracted attention because of
their low toxicity, biodegradability, and ecological acceptability. However
, for reasons of functionality and production cost, they are not competitiv
e with chemical surfactants. Use of inexpensive substrates can drastically
decrease the production cost of biosurfactants. This review describes the u
se of unconventional carbon sources for biosurfactant production. These sou
rces include urban as well as agroindustrial wastes. With suitable engineer
ing and microbiological modifications, these wastes can be used as substrat
es for large-scale production of biosurfactants.