Facile formation of a titanium-carbon bond from TiCl4 by HCl elimination: the synthesis and structure of TiCl3[Me3SiNP(Ph)(2)-CHCH2P(Ph)(2)NSiMe3]

Authors
Sarsfield, MJ Thornton-Pett, M Bochmann, M
Citation
Mj. Sarsfield et al., Facile formation of a titanium-carbon bond from TiCl4 by HCl elimination: the synthesis and structure of TiCl3[Me3SiNP(Ph)(2)-CHCH2P(Ph)(2)NSiMe3], J CHEM S DA, (19), 1999, pp. 3329-3330
Citations number
23
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
03009246 → ACNP
Issue
19
Year of publication
1999
Pages
3329 - 3330
Database
ISI
SICI code
0300-9246(1999):19<3329:FFOATB>2.0.ZU;2-8
Abstract
The reaction of TiCl4 with the bis-phosphinimine Me3SiN=P(Ph)(2)CH2CH2P(Ph) (2)=NSiMe3 1 proceeds with evolution of HCl and metallation of one CH2 grou p to give TiCl3{Me3SiNP(Ph)(2)CHCH2P(Ph)(2)NSiMe3} 2. The crystal structure of 2 is solved and shows a comparatively long Ti-C bond.