I. Dierking et al., Horizontal chevron domain formation and smectic layer reorientation in SmC* liquid crystals stabilized by polymer networks, LIQ CRYST, 26(10), 1999, pp. 1511-1519
The influence of a polymer network, stabilizing an initial texture of horiz
ontal chevron geometry, on the in-plane smectic C* layer reorientation proc
ess is studied for different applied electric field conditions. As expected
, the reorientation of smectic layers is strongly slowed down and eventuall
y suppressed by the network, even at rather low monomer concentrations. Pol
ymer network formation in a uniformly reoriented smectic layer state reveal
s that the network acts in two ways: first it gives a biased elastic torque
counteracting a field of such symmetry as to cause a change from the templ
ated layer direction; second it introduces an increased effective viscosity
counteracting the reorientation in both directions. The behaviour of sampl
es stabilized by two different kinds of polymer networks, created in betwee
n the smectic layers (intra-layer) and across them (inter-layer), is then i
nvestigated and discussed.