Xj. Jin et al., Thermodynamic consideration of antiferromagnetic transition on fcc(gamma)-> hcp(epsilon) martensitic transformation in Fe-Mn-Si shape memory alloys, MATER CH PH, 61(2), 1999, pp. 135-138
On the basis of the empirical equations of Fe-Mn system and experimental in
formation, T-N(gamma) and T-N(epsilon), Neel temperatures of fcc(gamma) and
hcp(epsilon) phases in Fe-Mn-Si shape memory alloys have been evaluated as
follows: T-N,FeMn,Si(gamma) = 67x(Fe) + 540x(Mn) [761 + 689(x(Fe) - x(Mn))
]850x(Si); T-N,FeMnSi(epsilon) = 580x(Mn). Mn increases and Si decreases th
e Neel temperature of austenite. The antiferromagnetic transition influence
s the Gibbs energy of fcc(gamma) and hcp(epsilon) phases in Fe-Mn-Si alloys
. Therefore, addition of Si increases the driving force of martensitic tran
sformation in Fe-Mn-Si alloy. (C) 1999 Elsevier Science S.A. All rights res
erved.