Cu(CO)(2)(N(SO2CF3)(2)). The first structurally characterized copper(I) polycarbonyl

Authors
Polyakov, OG Ivanova, SM Gaudinski, CM Miller, SM Anderson, OP Strauss, SH
Citation
Og. Polyakov et al., Cu(CO)(2)(N(SO2CF3)(2)). The first structurally characterized copper(I) polycarbonyl, ORGANOMETAL, 18(19), 1999, pp. 3769-3771
Citations number
73
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
18
Issue
19
Year of publication
1999
Pages
3769 - 3771
Database
ISI
SICI code
0276-7333(19990913)18:19<3769:CTFSCC>2.0.ZU;2-B
Abstract
The title compound contains a three-coordinate Cu+ ion bonded to the sulfon amide nitrogen atom and to two CO ligands with Long Cu-C bonds (1.90 and 1. 91 Angstrom) and a C-Cu-C bond angle of 122 degrees. The two nu(CO) IR band s for this compound are at 2158 (s) and 2184 (m) cm(-1).