The simple and accurate gas chromatographic method proposed by us for the m
easurement of isothermal phase equilibrium has been used to study eight bin
ary mixtures of different types of polar compounds such as: aliphatic alcoh
ols (methanol, ethanol, propanol, butanol and pentanol), ketones (acetone a
nd methyl-iso-butyl ketone), ethylacetate and chlorobenzene. The results of
the present work on the binary mixtures of: acetone with methanol, and eth
ylacetate with methanol, ethanol and n-propanol are in good agreement with
literature data.