Interdiffusion coefficient and dynamic viscosity for the mixture 2,6-lutidine plus water near the lower consolute point

Citation
Jc. Clunie et Jk. Baird, Interdiffusion coefficient and dynamic viscosity for the mixture 2,6-lutidine plus water near the lower consolute point, PHYS CHEM L, 37(4), 1999, pp. 357-371
Citations number
44
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
PHYSICS AND CHEMISTRY OF LIQUIDS
ISSN journal
00319104 → ACNP
Volume
37
Issue
4
Year of publication
1999
Pages
357 - 371
Database
ISI
SICI code
0031-9104(1999)37:4<357:ICADVF>2.0.ZU;2-Z
Abstract
The mixture, 2,6-lutidine + water has a lower consolute point at a temperat ure of 33.9 degrees C and a lutidine concentration of 2.78 M. The interdiff usion coefficient of this mixture was measured over a wide range of concent rations along the isotherms at 25.00 degrees C and 33.00 degrees C, and ove r a wide range of temperatures along the critical isopleth. Critical slowin g down of diffusion was evident along all three paths. The dynamic viscosit y was measured along the isotherm at 25.00 degrees C and along the critical isopleth at temperatures below critical. Along the critical isopleth, the viscosity increased rapidly as the critical temperature was approached. The se data are discussed in terms of the cross-over function theory, which is used to connect divergent data near the critical point to smoothly varying data away from the critical point.