Vf. Kurenkov et Va. Myagchenkov, Features of radical polymerization and copolymerization of strong unsaturated electrolytes, RUS J AP CH, 72(6), 1999, pp. 921-930
Specific features of radical polymerization and copolymerization of strong
unsaturated electrolytes are characterized for the example of p-styrenesulf
onic acid salts in aqueous, aqueous-salt, and aqueous-organic solutions, ta
king into account the state of ionizable groups of monomers and macroradica
ls. The main factors complicating description of polymerization and copolym
erization in such systems are related to the non-isoionicity of the process
and diverse forms of the ionizable groups of the monomers and macroradical
s. General features of counterion binding in solutions of polymers and copo
lymers based on p-styrenesulfonic acid salts are considered.