Plasma immersion ion implantation technology was used to produce expanded a
ustenite and to study the influence of treatment conditions and starting ma
terial on its formation and structure. Standard materials characterisation
techniques, XRD, TEM, conversion electron Mossbauer spectroscopy, and Ruthe
rford backscatter spectrometry analysis were used to determine the structur
e of the layers, thereby revealing the complex structure of expanded austen
ite. The properties of the expanded austenite layers (hardness, wear; and c
orrosion) were determined and correlated with the structure. Most work was
concentrated on the austenitic stainless steel X6CrNiTi1810 after treatment
s at 300 and 400 degrees C. Based on these results, the possibilities of in
fluencing properties by varying the process conditions are discussed.