Cleavage of S-S bond by Sm/cat. CoCl2 or Sm/cat. CoCl2 center dot 6H(2)O system: A novel method for the synthesis of thiolesters

Authors
Chen, RN Zhang, YM
Citation
Rn. Chen et Ym. Zhang, Cleavage of S-S bond by Sm/cat. CoCl2 or Sm/cat. CoCl2 center dot 6H(2)O system: A novel method for the synthesis of thiolesters, SYN COMMUN, 29(21), 1999, pp. 3699-3704
Citations number
19
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNTHETIC COMMUNICATIONS
ISSN journal
00397911 → ACNP
Volume
29
Issue
21
Year of publication
1999
Pages
3699 - 3704
Database
ISI
SICI code
0039-7911(1999)29:21<3699:COSBBS>2.0.ZU;2-V
Abstract
The Sm/cat. CoCl2 or Sm/cat. CoCl2 . 6H(2)O system promoted disulfides to r eact with anhydrides or acyl chlorides to afford thiolesters in good yields under mild and neutral conditions.