A novel stereoselective synthesis of maleate derivatives via palladium-catalyzed dicarboalkoxylation of terminal alkynes

Authors
Li, JH Jiang, HF Jia, LQ
Citation
Jh. Li et al., A novel stereoselective synthesis of maleate derivatives via palladium-catalyzed dicarboalkoxylation of terminal alkynes, SYN COMMUN, 29(21), 1999, pp. 3733-3738
Citations number
11
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNTHETIC COMMUNICATIONS
ISSN journal
00397911 → ACNP
Volume
29
Issue
21
Year of publication
1999
Pages
3733 - 3738
Database
ISI
SICI code
0039-7911(1999)29:21<3733:ANSSOM>2.0.ZU;2-D
Abstract
Alkynes were dicarboalkoxylated efficiently and stereoselectively in high y ields reacting for about 2h under atmospheric pressure of carbon monoxide a t room temperature using a catalytic amount of PdCl2 and a stoichiometric a mount of CuCl2.