Accurate calculation of vibrational resonances by perturbation theory

Citation
Fm. Fernandez et Rh. Tipping, Accurate calculation of vibrational resonances by perturbation theory, THEOCHEM, 488, 1999, pp. 157-161
Citations number
13
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
THEOCHEM-JOURNAL OF MOLECULAR STRUCTURE
ISSN journal
01661280 → ACNP
Volume
488
Year of publication
1999
Pages
157 - 161
Database
ISI
SICI code
0166-1280(19991001)488:<157:ACOVRB>2.0.ZU;2-J
Abstract
We construct rapidly convergent algebraic approximants from the perturbatio n series for anharmonic oscillators and obtain accurate resonance energies for the quartic oscillator with a negative coupling. The approximants take into account analytic properties of the eigenvalues. We compare our results with previous calculations performed by other authors. (C) 1999 Elsevier S cience B.V. All rights reserved.