The largest accumulations of natural gas occur in shallow Cenomanian reserv
oir sands of the Pokur Formation in the northern part of the West Siberian
basin, Various theories on the origin of this gas were developed in the pas
t, To evaluate these theories, a large set of gas and rock samples was stud
ied using organic geochemical methods. Our results reveal that early thermo
genic methane generation can explain the isotopic composition of the natura
l gas in this area, but not the extreme dryness. In particular, the isotopi
c composition of early thermogenic methane generated upon laboratory pyroly
sis is in accordance with that of the methane in the large gas accumulation
s of northern west Siberia (delta(13)C approximate to -45 to -55 parts per
thousand). The quantities of early thermogenic gas generated according to o
ur calculations, however, are not sufficient to explain the largest accumul
ations. The huge amount of gas in the reservoirs is explained by degassing
of methane-saturated pore water, mainly as a consequence of Neogene uplift
of the basin, Since the late Eocene, the movement of water from the souther
n to the northern part of the basin enlarged the effective catchment area o
f the gas fields.