Citation
L. Cheng et al., Structural consequences of hydroxamate and tropolonate binding to iron porphyrins, CHEM COMMUN, (19), 1999, pp. 1941-1942
Citations number
17
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345
→ ACNP
Issue
19
Year of publication
1999
Pages
1941 - 1942
Database
ISI
SICI code
1359-7345(19991007):19<1941:SCOHAT>2.0.ZU;2-C
Abstract
The solid-state structures of iron porphyrin hydroxamate complexes reveal a
n unusual monodentate eta(1)-O binding mode; the bidentate eta(2)-O,O bindi
ng of the tropolonate anion results in an apical displacement of iron of 0.
80 Angstrom from the 24-atom mean porphyrin plane.