An improved vinylalumination procedure replacing HMPA with NMO for the hydroalumination of alpha-acetylenic esters and ketones

Authors
Ramachandran, PV Reddy, MVR Rudd, MT
Citation
Pv. Ramachandran et al., An improved vinylalumination procedure replacing HMPA with NMO for the hydroalumination of alpha-acetylenic esters and ketones, CHEM COMMUN, (19), 1999, pp. 1979-1980
Citations number
12
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
19
Year of publication
1999
Pages
1979 - 1980
Database
ISI
SICI code
1359-7345(19991007):19<1979:AIVPRH>2.0.ZU;2-K
Abstract
Replacing carcinogenic HMPA with NMO, a higher yielding, enviornmentally be nign procedure for the vinylalumination of carbonyl compounds with [alpha-( ethoxycarbonyl)- vinyl]diisobutylaluminium and its beta-methyl or -phenyl a nalogs, as well as [alpha-(acetyl)vinyl]diisobutylaluminium has been develo ped.