Photo-induced metastable linkage isomers of ruthenium nitrosyl porphyrins

Authors
Fomitchev, DV Coppens, P Li, TS Bagley, KA Chen, L Richter-Addo, GB
Citation
Dv. Fomitchev et al., Photo-induced metastable linkage isomers of ruthenium nitrosyl porphyrins, CHEM COMMUN, (19), 1999, pp. 2013-2014
Citations number
43
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
19
Year of publication
1999
Pages
2013 - 2014
Database
ISI
SICI code
1359-7345(19991007):19<2013:PMLIOR>2.0.ZU;2-R
Abstract
IR spectroscopic results, combined with earlier crystallographic and spectr oscopic evidence on Fe and Ru nitrosyl complexes, indicate that metastable eta(1)-O and eta(2)-NO linkage isomers are formed on low-temperature irradi ation of the nitrosyl metalloporphyrins (OEP)Ru(NO)L (L = O-i-C5H11, SCH2CF 3); the new compounds are stable at low temperature, but revert to the grou nd state on warming.