THERMAL INTERCONVERSIONS OF THE C16H10 CYCLOPENTA-FUSED POLYCYCLIC AROMATIC-HYDROCARBONS FLUORANTHENE, ACEPHENANTHRYLENE AND ACEANTHRYLENE REVISITED

The thermal interconversion of the C16H10 cydopenta-fused polycyclic a romatic hydrocarbons (CP-PAH) fluoranthene (1), acephenanthrylene (2) and aceanthrylene (3) has been studied using Flash Vacuum Thermolysis (FVT). In contrast to previously reported flow-pyrolysis results, whic h gave the unexpected thermodynamic stability order 1 > 3 > 2, FVT tem perature-canversion data unequivocally show the extended order 1 > 2 > 3. These results are supported by independent FVT experiments with 9- ethynylphenanthrene (4), 9-ethynylanthracene (5) and 5-(anthryl-9'-met hylene)-2, 2-dimethyl-1,3-dioxan-4,6-dione (6), which are precursors f or acephenanthrylene (2) and aceanthrylene (3), respectively. The inte rpretation of the FVT results is corroborated by semiempirical AM1 cal culations of the C16H10 potential energy surface.