Vf. Shvets et al., KINETIC FEATURES OF THE REACTION BETWEEN ETHYLENE-OXIDE AND PHENOL, Theoretical foundations of chemical engineering, 31(3), 1997, pp. 236-240
A mathematical model for the production of beta-phenoxy ethanol by the
addition reaction between ethylene oxide and phenol catalyzed by sodi
um hydroxide is proposed. The model fits the behavior of all component
s in the reaction mixture adequately. The model is analyzed for isothe
rmal conditions. The result of this analysis is a correlation that rel
ates the three most important process parameters: temperature, catalys
t concentration, and residual phenol concentration. The reaction in qu
estion proceeding in a polytropic plug-flow reactor is simulated. The
results of this simulation indicate that the correlation holds true fo
r the maximum temperature of the flow in the reactor. An algorithm to
calculate the parameters of a tubular reactor for the production of be
ta-phenoxy ethanol is proposed. The algorithm makes it possible to cho
ose operating conditions under which the residual phenol concentration
in the product meets the process specifications.