KINETIC FEATURES OF THE REACTION BETWEEN ETHYLENE-OXIDE AND PHENOL

Citation
Vf. Shvets et al., KINETIC FEATURES OF THE REACTION BETWEEN ETHYLENE-OXIDE AND PHENOL, Theoretical foundations of chemical engineering, 31(3), 1997, pp. 236-240
Citations number
3
Categorie Soggetti
Engineering, Chemical
ISSN journal
00405795
Volume
31
Issue
3
Year of publication
1997
Pages
236 - 240
Database
ISI
SICI code
0040-5795(1997)31:3<236:KFOTRB>2.0.ZU;2-G
Abstract
A mathematical model for the production of beta-phenoxy ethanol by the addition reaction between ethylene oxide and phenol catalyzed by sodi um hydroxide is proposed. The model fits the behavior of all component s in the reaction mixture adequately. The model is analyzed for isothe rmal conditions. The result of this analysis is a correlation that rel ates the three most important process parameters: temperature, catalys t concentration, and residual phenol concentration. The reaction in qu estion proceeding in a polytropic plug-flow reactor is simulated. The results of this simulation indicate that the correlation holds true fo r the maximum temperature of the flow in the reactor. An algorithm to calculate the parameters of a tubular reactor for the production of be ta-phenoxy ethanol is proposed. The algorithm makes it possible to cho ose operating conditions under which the residual phenol concentration in the product meets the process specifications.