Structure and characterization of a mononuclear Fe-II dialkyldithiocarbamate complex Fe(OC(4)H(8)dtc)(2)(DMF)

Authors
Deng, YH Wen, TB Liu, QT Zhu, HP Chen, CN Wu, DX
Citation
Yh. Deng et al., Structure and characterization of a mononuclear Fe-II dialkyldithiocarbamate complex Fe(OC(4)H(8)dtc)(2)(DMF), INORG CHIM, 293(1), 1999, pp. 95-99
Citations number
26
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANICA CHIMICA ACTA
ISSN journal
00201693 → ACNP
Volume
293
Issue
1
Year of publication
1999
Pages
95 - 99
Database
ISI
SICI code
0020-1693(19991002)293:1<95:SACOAM>2.0.ZU;2-5
Abstract
A ferrous dialkyldithiocarbamate complex Fe(OC(4)H(8)dtc)(2)(DMF), which co ntains a Fe atom with distorted square pyramidal geometry and forms a netwo rk structure by intermolecular C-H ... S and C-H ... O interactions has bee n obtained and structurally characterized. Proton NMR and IR spectra have b een studied. Structural parameters and Mossbauer effect indicate the oxidat ion state of + 2 for the Fe site. A very large quadrupole splitting of 4.10 mm s(-1) was observed and associated with an asymmetric 3d(6)(t(2g)(4)e(g) (2)) electronic configuration. (C) 1999 Elsevier Science S.A. All rights re served.