Anisotropic arrangement of Mo species highly dispersed on TiO2(110) surface demonstrated by polarization dependent total reflection fluorescence EXAFS

Authors
Asakura, K Chun, WJ Iwasawa, Y
Citation
K. Asakura et al., Anisotropic arrangement of Mo species highly dispersed on TiO2(110) surface demonstrated by polarization dependent total reflection fluorescence EXAFS, JPN J A P 1, 38, 1999, pp. 40-43
Citations number
12
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS → ACNP
Volume
38
Year of publication
1999
Supplement
1
Pages
40 - 43
Database
ISI
SICI code
Abstract
Mo species on TiO2(110) surface were studied by means of Polarization Depen dent Total Reflection Fluorescence EXAFS. The structure and orientation of Mo species are strongly affected by the pretreatment conditions and impurit y. Mo dimer oriented to [1<1(1)over bar 0 >] direction and Mo chain structu re along [001] are present when they are prepared under oxidative condition s and reductive conditions, respectively. On the other hand, Mo tetrahedral monomer is formed when Na+ and K+ are present on the surface.