Ah. Shinohara et al., Effect of heat treatment on the high-purity silica glass prepared from amorphous and crystalline powders by small angle X-ray scattering, JPN J A P 1, 38, 1999, pp. 136-139
High-purity silica glass prepared from high-purity amorphous and crystallin
e powders by flame fusion and sintering at high temperatures in vacuum, was
heat-treated at 1250 degrees C for several periods of time and its structu
re was studied using the small-angle X-ray scattering technique. As a resul
t, the structure of silica glass was dependent on its thermal history. The
structure of as-fused silica glass samples prepared by flame fusion appeare
d to be quite similar, even though raw materials with different degrees of
homogeneity were used. However, the structure of silica glass behaved diffe
rently after heat treatment. This different response of the structure of si
lica glass to heat treatment was analyzed in terms of impurity content and
viscosity.