The energy-dispersive X-ray diffraction measurements using synchrotron radi
ation at SPring-8 for expanded fluid Hg were carried out in the wide densit
y range from the liquid to the dense vapour region including the metal-nonm
etal (M-NM) transition region. Density ranges from 13.6 to 1.9 gcm(-3). We
obtained the structure factor S(k) and the pair distribution functions g(r)
. The density variations of the obtained interatomic distance and coordinat
ion number were discussed in relation to the M-NM transition in fluid Hg.