A radio-frequency CF4 plasma in reactive-ion etcher with parallel plate geo
metry is investigated in one dimension at a position space using the relaxa
tion continuum model. The discharge with negative ions has the double layer
similar in appearance to O-2; the structure and mechanism are markedly cha
nged as a function of driving frequency. The effect of driving frequency is
numerically studied between 13.56 MHz and 200 MHz for 200 mTorr and 50 mTo
rr. In these studies, the plasma density is kept constant at similar to 10(
11) cm(-3), considering the charged species CF3+, CF2+, CF+, C+, F+, F-, an
d electrons. The mean energy of charged particles is also discussed.