Hm. Jeon et al., Effect of oxygen component in magneto-active microwave CH4/He plasma on large-area diamond nucleation over Si, JPN J A P 1, 38(7B), 1999, pp. 4500-4503
Nucleation-enhanced pretreatments have been studied for large-area diamond
growth on Si (100) substrates using magnetoactive microwave plasma chemical
vapor deposition (CVD) at low pressures below 10 Pa. In this study, an opt
imal CO2 composition in the CH4/He plasma used for the pretreatment was mai
nly examined for the case of a low substrate temperature of similar to 600
degrees C. A two-hour subsequent growth using a CH4 [5 sccm]/CO2[10 sccm]/H
-2 [85 sccm] gas mixture after the pre treatment resulted in [100]-oriented
growth of diamond Particles with a high density (similar to 10(9)/cm(2)) o
n Si substrates pretreated at CO2 concentrations of 1-2%. On the other hand
, at CO2 concentrations higher than these, the carbon films deposited durin
g the pretreatment were less dense and were almost completely etched off af
ter a 10-min treatment using the growth plasma. It was found that quadrupol
e mass spectra, optical emission spectra and Raman scattering spectra chang
ed substantially when CO2 beyond 3.8% was added to the source gas.