Single crystals of the new host Ba12F19Cl5 doped with Eu2+ were grown and s
tudied by electron paramagnetic resonance (EPR) and luminescence emission s
pectroscopy. Three different Eu2+ sites were observed. Two of them had orth
orhombic point symmetry while the last one was monoclinic. Physico-chemical
and symmetry arguments allowed us to establish correspondence between the
different Eu2+ centres and the host cation lattice sites. All three centres
presented in their ground state important crystal field splitting. The 80
K luminescence emission spectrum consisted of one broad unsymmetrical f-d b
and peaking at 22 700 cm(-1). No 4f-4f transitions of the Eu2+ ion were obs
erved between room temperature and 80 K.