EPR and optical investigation of europium doped Ba12F19Cl5

Citation
Jm. Rey et al., EPR and optical investigation of europium doped Ba12F19Cl5, J PHYS-COND, 11(38), 1999, pp. 7301-7309
Citations number
21
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
JOURNAL OF PHYSICS-CONDENSED MATTER
ISSN journal
09538984 → ACNP
Volume
11
Issue
38
Year of publication
1999
Pages
7301 - 7309
Database
ISI
SICI code
0953-8984(19990927)11:38<7301:EAOIOE>2.0.ZU;2-A
Abstract
Single crystals of the new host Ba12F19Cl5 doped with Eu2+ were grown and s tudied by electron paramagnetic resonance (EPR) and luminescence emission s pectroscopy. Three different Eu2+ sites were observed. Two of them had orth orhombic point symmetry while the last one was monoclinic. Physico-chemical and symmetry arguments allowed us to establish correspondence between the different Eu2+ centres and the host cation lattice sites. All three centres presented in their ground state important crystal field splitting. The 80 K luminescence emission spectrum consisted of one broad unsymmetrical f-d b and peaking at 22 700 cm(-1). No 4f-4f transitions of the Eu2+ ion were obs erved between room temperature and 80 K.