New principle of molecular design of LC polymers by covalent and ionic bonding of side groups

Authors
Barmatov, E Barmatova, M Chenskaya, T Shibaev, V
Citation
E. Barmatov et al., New principle of molecular design of LC polymers by covalent and ionic bonding of side groups, MOL CRYST A, 332, 1999, pp. 2941-2948
Citations number
20
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS
ISSN journal
1058725X → ACNP
Volume
332
Year of publication
1999
Pages
2941 - 2948
Database
ISI
SICI code
1058-725X(1999)332:<2941:NPOMDO>2.0.ZU;2-3
Abstract
The combined principle to design comb-shaped LC polymers by covalent and io nic bonding of side groups with the main chain was suggested. The ionic com plexes formed by a LC copolymers containing similar to 29 mol% of acrylic a cid and octadecylamine were received. A study of phase behaviour of ionic c omplexes revealed the role that a low-molecular non-mesogenic component, at tached through a non-covalent linkage to the main chain of the polymer, can play in the structure and properties of such ionic complexes.