Temperature dependence of visco-elastic properties of 5CB

Authors
Citation
M. Cui et Jr. Kelly, Temperature dependence of visco-elastic properties of 5CB, MOL CRYST A, 331, 1999, pp. 1909-1917
Citations number
15
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS
ISSN journal
1058725X → ACNP
Volume
331
Year of publication
1999
Part
4
Pages
1909 - 1917
Database
ISI
SICI code
1058-725X(1999)331:<1909:TDOVPO>2.0.ZU;2-2
Abstract
Visco-elastic properties of 5CB as a function of temperature in the nematic region are studied. Three Miesowicz viscosity coefficients eta(a), eta(b) and eta(c) and rotational viscosity gamma(1) are determined by dynamic ligh t scattering (DLS) measurements. By assuming alpha(3) = 0, other Leslie vis cosity coefficients are also calculated. Fitting our gamma(1) data to Osipo v and Terentjev's theory, a coupling constant of 3.14k(B)T(c) is obtained, which is smaller than the mean field theory value. Temperature dependence o f order parameter is obtained from refractive index measurement: using Hall er's method. To obtain accurate viscosity parameters from DLS, accurate val ues of elastic constants are required. Three different techniques are used to determine K-11, K-22 and K-33, respectively: fitting the electric field dependence of capacitance to nematic continuum theory, ac electric field DL S and magnetic Freedericksz transition.