Citation
I. Terrien et al., Side-on fixed liquid crystalline polymers: New stationary phases for high performance liquid chromatography, MOL CRYST A, 331, 1999, pp. 2291-2298
Citations number
8
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS
ISSN journal
1058725X
→ ACNP
Volume
331
Year of publication
1999
Part
4
Pages
2291 - 2298
Database
ISI
SICI code
1058-725X(1999)331:<2291:SFLCPN>2.0.ZU;2-8
Abstract
New stationary phases are obtained by coating on a silica support liquid cr
ystalline polysiloxanes with mesogenic side groups laterally attached to th
e polymer backbone through the flexible spacer. They show very good chromat
ographic performances in HPLC for the separation of polycyclic aromatic hyd
rocarbons. Solute/mesogenic group interactions are evaluated through molecu
lar mechanics calculations and correlated to the chromatographic results.