A wave function expansion for the study of tetra-atomic molecules in hyperspherical coordinate systems

Citation
Ls. Costa et Jjs. Neto, A wave function expansion for the study of tetra-atomic molecules in hyperspherical coordinate systems, MOLEC PHYS, 97(6), 1999, pp. 725-730
Citations number
29
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
MOLECULAR PHYSICS
ISSN journal
00268976 → ACNP
Volume
97
Issue
6
Year of publication
1999
Pages
725 - 730
Database
ISI
SICI code
0026-8976(19990920)97:6<725:AWFEFT>2.0.ZU;2-D
Abstract
In this work, we focus on the tetra-atomic molecule problem in hyperspheric al coordinates. In particular, we explore the system of hyperspherical coor dinates as used, for example, by Ohrn and Linderberg (1983, Molec. Phys., 4 9, 53). We consider a wave function expansion which facilitates the analyti c integration of the kinetic energy operator for the nine degrees of freedo m.