The ab initio absorption spectra of GanAsm clusters (n+m less than or equal
to 10) are calculated using a time-dependent density-functional formalism
within the local density approximation. We find the photoabsorption gaps co
mputed at 2% of the total absorption to be in good agreement with experimen
t. A rich variety of spectral shapes for clusters with different structures
may help to identify isomers. The calculated spectra exhibit long absorpti
on tails extending deep into the region of the lower transition energies. S
uch behavior can be attributed to the existence of free surfaces in cluster
s.