Brillouin spectroscopy of porous Si (pi-Si) formed on p-type (100) Si has r
evealed two acoustic-phonon peaks associated with the surface and film mode
s of the thick porous slab. They exhibit relatively large peak widths that
are attributed to fractons. Longitudinal wave guiding is enhanced in high p
orosity pi-Si due to its very low sound velocities compared with Si. Unlike
opaque semiconductors where ripple scattering is dominant, the elasto-opti
c contribution to the scattering mechanism is found to be significant in pi
-Si. Both phonon velocities show appreciable negative dispersion due to a p
orosity gradient.