Magnetization processes in advanced magnetic nanostructures are investigate
d. For the case of spherical soft or semihard grains surrounded by a very h
ard matrix a bulging nucleation mode is discovered. The bulging mode exhibi
ts the radial angular symmetry of the coherent mode, but it is incoherent d
ue to its radial variation. The radial dependence of the bulging mode is ob
tained by solving a spherical Bessel equation which is subject to appropria
te boundary conditions. In contrast to the coherent mode, the bulging mode
yields a nucleation-field coercivity which depends on the exchange stiffnes
s and on the size of the grain. There is a critical grain radius 7.869 root
A/mu(0)M(s)(2) above which the bulging mode is replaced by a modified curl
ing mode. The nucleation modes realized in nanostructures affect the demagn
etizing-field corrections necessary to account for the external shape of ma
gnetic samples. Since strong but short-range exchange and weak but long-ran
ge magnetostatic interactions compete on nanostructural length scales, the
sample-shape dependence of the hysteresis loops cannot be mapped onto a pur
ely magnetostatic demagnetizing factor. [S0163-1829(99)01734-8].