We have performed optical reflectivity experiments and band structure diffr
action calculations on fee photonic crystals, consisting of air spheres in
titania (TiO2). The spectra reveal Bragg peaks whose large widths agree wel
l with the calculations. The peaks overlap in many directions, causing the
propagation of light to be limited by Bragg reflection to 45% of the 4 pi s
olid angler This illustrates that the air-sphere crystals interact so stron
gly with light that an unprecedented limitation in the directions of propag
ation of light in photonic crystals is achieved.