OXIDATION OF ORGANIC SULFIDES WITH CLAY-SUPPORTED IODOSYLBENZENE AS OXYGEN DONOR

Authors
KANNAN P SEVVEL R RAJAGOPAL S PITCHUMANI K SRINIVASAN C
Citation
P. Kannan et al., OXIDATION OF ORGANIC SULFIDES WITH CLAY-SUPPORTED IODOSYLBENZENE AS OXYGEN DONOR, Tetrahedron, 53(22), 1997, pp. 7635-7640
Citations number
46
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
53
Issue
22
Year of publication
1997
Pages
7635 - 7640
Database
ISI
SICI code
0040-4020(1997)53:22<7635:OOOSWC>2.0.ZU;2-E
Abstract
Alkyl, aryl and diaryl sulfides afford excellent yields of sulfoxides with PhIO supported on natural (montmorillonite, KSF and bentonite cla y) as well as cation-exchanged clays of K10-montmorillonite in acetoni trile suspension and also in solid state. A Ligand coupling mechanism for this facile oxidation is proposed. (C) 1997 Elsevier Science Ltd.