Model for the hydrogen sorption by a metal with potential varied in a cyclic stepwise manner

Citation
Yb. Skuratnik et al., Model for the hydrogen sorption by a metal with potential varied in a cyclic stepwise manner, RUSS J ELEC, 35(9), 1999, pp. 927-933
Citations number
9
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
RUSSIAN JOURNAL OF ELECTROCHEMISTRY
ISSN journal
10231935 → ACNP
Volume
35
Issue
9
Year of publication
1999
Pages
927 - 933
Database
ISI
SICI code
1023-1935(199909)35:9<927:MFTHSB>2.0.ZU;2-G
Abstract
Expressions are derived for theta, which is the coverage of a metal surface by hydrogen atoms occurring when the potential is varied in a cyclic stepw ise manner at different frequencies f, amplitudes, and mark-to-space ratios . It is shown that, at sufficiently high f, theta tends to a quasi-steady-s tate value which depends on the amplitude and mark-to-space ratio of a cycl ic pulse. The dependence of theta on the hydrogen diffusion in the metal is analyzed.