Electrochemical metallation and arylation of C-60

Authors
Magdesieva, TV Bashilov, VV Kravchuk, DN Sokolov, VI Butin, KP
Citation
Tv. Magdesieva et al., Electrochemical metallation and arylation of C-60, RUSS J ELEC, 35(9), 1999, pp. 992-999
Citations number
27
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
RUSSIAN JOURNAL OF ELECTROCHEMISTRY
ISSN journal
10231935 → ACNP
Volume
35
Issue
9
Year of publication
1999
Pages
992 - 999
Database
ISI
SICI code
1023-1935(199909)35:9<992:EMAAOC>2.0.ZU;2-S
Abstract
Electrochemically activated reactions of metallation and arylation of C-60 are examined. A convenient method of synthesizing exohedral complexes of th e C60ML2 type (M = Pd, Pt; L = Ph3P) is developed. The method is based on t he electrochemical generation of anions C-60(2-) and their subsequent react ion with complexes [M(Ph3P)(2)Cl-2, MCl2] of bivalent metals. A possibility of realizing electrochemically activated reactions of fullerene arylation by means of Ph2IBF4 is shown.