anti-aldol selective tandem Michael/aldol reaction with magnesium selenolate and stereoselective preparation of tetrasubstituted tetrahydrofuran

Authors
Mitsudera, H Kakehi, A Kamimura, A
Citation
H. Mitsudera et al., anti-aldol selective tandem Michael/aldol reaction with magnesium selenolate and stereoselective preparation of tetrasubstituted tetrahydrofuran, TETRAHEDR L, 40(41), 1999, pp. 7389-7392
Citations number
24
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
40
Issue
41
Year of publication
1999
Pages
7389 - 7392
Database
ISI
SICI code
0040-4039(19991008)40:41<7389:ASTMRW>2.0.ZU;2-X
Abstract
Magnesium selenolate-induced Michael/aldol tandem reaction resulted in the anti-aldol selective formation of beta-hydroxy-beta-(phenylseleno)alkyl est ers, which were readily converted into tetrasubstituted tetrahydrofurans in a good 2,3-cis-3,4-trans-4,5-trans-selective manner. (C) 1999 Elsevier Sci ence Ltd. All rights reserved.