Catalytic asymmetric synthesis of glycidic amides via chiral sulfur ylides

Authors
Imashiro, R Yamanaka, T Seki, M
Citation
R. Imashiro et al., Catalytic asymmetric synthesis of glycidic amides via chiral sulfur ylides, TETRAHEDR-A, 10(15), 1999, pp. 2845-2851
Citations number
19
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON-ASYMMETRY
ISSN journal
09574166 → ACNP
Volume
10
Issue
15
Year of publication
1999
Pages
2845 - 2851
Database
ISI
SICI code
0957-4166(19990730)10:15<2845:CASOGA>2.0.ZU;2-H
Abstract
Reaction of diazoacetamides with aromatic aldehydes in the presence of 20 m ol% of chiral binaphthylsulfide and 10 mol% of copper(II) acetylacetonate g ave chiral glycidic amides with up to 64% ee. (C) 1999 Elsevier Science Ltd . All rights reserved.