Atropo-enantioselective synthesis of an axially chiral C-1-symmetric phosphine ligand and its application in the asymmetric hydrosilylation of styrenes

Authors
Bringmann, G Wuzik, A Breuning, M Henschel, P Peters, K Peters, EM
Citation
G. Bringmann et al., Atropo-enantioselective synthesis of an axially chiral C-1-symmetric phosphine ligand and its application in the asymmetric hydrosilylation of styrenes, TETRAHEDR-A, 10(15), 1999, pp. 3025-3031
Citations number
24
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON-ASYMMETRY
ISSN journal
09574166 → ACNP
Volume
10
Issue
15
Year of publication
1999
Pages
3025 - 3031
Database
ISI
SICI code
0957-4166(19990730)10:15<3025:ASOAAC>2.0.ZU;2-M
Abstract
The axially chiral monodentate phosphine P-8 was synthesized in enantiomeri cally pure form, starting from the readily available, configurationally uns table lactone 1. Furthermore, its application as a ligand in the Pd-catalyz ed stereoselective hydrosilylation of styrenes was investigated. (C) 1999 E lsevier Science Ltd. All rights reserved.