Soft template synthesis of (2,8-dithio-3,7-diaza-5-oxanonandithioamide-1,9) nickel(II) and (2,7-dithio-3,6-diazaoctadien-3,5-dithioamide-1,8)nickel(II) using a nickel(II)hexacyanoferrate(II) gelatin-immobilized matrix

Authors
Mikhailov, OV Khamitova, AI Shigapova, LS Busygina, TE
Citation
Ov. Mikhailov et al., Soft template synthesis of (2,8-dithio-3,7-diaza-5-oxanonandithioamide-1,9) nickel(II) and (2,7-dithio-3,6-diazaoctadien-3,5-dithioamide-1,8)nickel(II) using a nickel(II)hexacyanoferrate(II) gelatin-immobilized matrix, TRANSIT MET, 24(5), 1999, pp. 503-510
Citations number
11
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
TRANSITION METAL CHEMISTRY
ISSN journal
03404285 → ACNP
Volume
24
Issue
5
Year of publication
1999
Pages
503 - 510
Database
ISI
SICI code
0340-4285(199910)24:5<503:STSO(>2.0.ZU;2-O
Abstract
Complexing processes leading under specific conditions to nickel(II)hexacya noferrate(II) gelatin-immobilized matrix systems in contact with aqueous-al kaline solutions (pH similar to 12) containing dithiooxamide and formaldehy de or glyoxal, have been studied. It has been shown that template synthesis of macrocyclic co-ordination compounds, (2,8-dithio-3,7-diaza-5-oxanonandi thioamide-1,9)nickel(II) and (2,7-dithio-3,6-diazaoctadien-3,5-dithioamide- 1,8)nickel(II), occurs. Dithiooxamide, formaldehyde and glyoxal act as liga nd synthons in this process.