Citation
M. Shakir et al., Macrocyclic complexes of transition metals with divalent polyaza units, TRANSIT MET, 24(5), 1999, pp. 577-580
Citations number
23
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
TRANSITION METAL CHEMISTRY
ISSN journal
03404285
→ ACNP
Volume
24
Issue
5
Year of publication
1999
Pages
577 - 580
Database
ISI
SICI code
0340-4285(199910)24:5<577:MCOTMW>2.0.ZU;2-G
Abstract
A new series of 14-16-membered hexaazamacrocyclic complexes [ML X-1(2)] and
[ML X-2(2)] (M = Co-II, Ni-II, Cu-II and Zn-II; X = Cl or NO3) have been s
ynthesized by template condensation of phenylenediamine, primary diamines a
nd formaldehyde solution 35% in MeOH and have been characterized by i.r., H
-1-n.m.r., e.p.r., and u.v. spectroscopy as well as by magnetic susceptibil
ity and conductivity measurements. An octahedral geometry has been suggeste
d for all the complexes.