Crystal structure and spectroscopic properties of a new five-coordinate mixed-ligand nickel(II) complex with a macrocyclic ligand: [Ni(trans[14]diene)SCN]ClO4 (trans[14]diene=5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene)

Authors
Shen, HY Liao, DZ Jiang, ZH Yan, SP
Citation
Hy. Shen et al., Crystal structure and spectroscopic properties of a new five-coordinate mixed-ligand nickel(II) complex with a macrocyclic ligand: [Ni(trans[14]diene)SCN]ClO4 (trans[14]diene=5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene), TRANSIT MET, 24(5), 1999, pp. 581-583
Citations number
12
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
TRANSITION METAL CHEMISTRY
ISSN journal
03404285 → ACNP
Volume
24
Issue
5
Year of publication
1999
Pages
581 - 583
Database
ISI
SICI code
0340-4285(199910)24:5<581:CSASPO>2.0.ZU;2-J
Abstract
A new five-coordinate nickel(II) complex of a trans[14]diene macrocyclic li gand has been prepared and characterized by X-ray crystallography, u.v. and i.r. spectroscopy. The coordination environment of the nickel(II) ion is a distorted square pyramid with the nickel(II) ion deviating from the level plane 0.25 Angstrom and the SCN ligand at the apical side.