Reactions of trimethylstibine in the superacidic systems XF/MF5 (X = H, D;M = As, Sb), crystal structures of (CH3)(3)SbD+SbF6- and (CH3)(3)SbSb(CH3)(3)(2+)(SbF6-)(2) center dot SO2

Authors
Minkwitz, R Hirsch, C
Citation
R. Minkwitz et C. Hirsch, Reactions of trimethylstibine in the superacidic systems XF/MF5 (X = H, D;M = As, Sb), crystal structures of (CH3)(3)SbD+SbF6- and (CH3)(3)SbSb(CH3)(3)(2+)(SbF6-)(2) center dot SO2, Z ANORG A C, 625(10), 1999, pp. 1674-1682
Citations number
31
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
625
Issue
10
Year of publication
1999
Pages
1674 - 1682
Database
ISI
SICI code
0044-2313(199910)625:10<1674:ROTITS>2.0.ZU;2-0
Abstract
The reaction of trimethylstibine in the superacidic systems XF/MF5 (M = As, Sb; X = H, D) leads to the trimethylstibonium hexafluorometallates. The re sulting salts are characterised by vibrational spectroscopy and their cryst al structures. Decomposition of trimethylstibonium hexafluoroantimonate in sulphur dioxide at room temperature ends in the formation of hexamethyldist ibonium bis(hexafluoroantimonate) as a sulphur dioxide adduct, verified by its crystal structure: and vibrational spectra.