A mixed transition metal molybdate, beta-(Co0.7Fe0.3)MoO4

Authors
Ehrenberg, H Svoboda, I Wiesmann, M Weitzel, H
Citation
H. Ehrenberg et al., A mixed transition metal molybdate, beta-(Co0.7Fe0.3)MoO4, ACT CRYST C, 55, 1999, pp. 1383-1384
Citations number
8
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
9
Pages
1383 - 1384
Database
ISI
SICI code
0108-2701(19990915)55:<1383:AMTMMB>2.0.ZU;2-6
Abstract
The high-temperature modification of the title mixed compound, cobalt iron molybdate, a transition metal molybdate of type beta-AMoO(4), with A = (Co0 .7Fe0.3), is metastable at room temperature. The distribution of Fe and Co is different for the two non-equivalent A sites: only 18 (9)% of all atoms on the 4i site are Fe, compared with 43 (9)% on the 4h site.