Zinc cadmium thiocyanate (ZCTC)

Citation
Yp. Tian et al., Zinc cadmium thiocyanate (ZCTC), ACT CRYST C, 55, 1999, pp. 1393-1395
Citations number
12
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
9
Pages
1393 - 1395
Database
ISI
SICI code
0108-2701(19990915)55:<1393:ZCT(>2.0.ZU;2-L
Abstract
The title complex, zinc cadmium tetrathiocyanate, [ZnCd(SCN)(4)](n), contai ns slightly flattened ZnN4 and CdS4 tetrahedra. The -S=C=N- bridges connect Zn and Cd atoms, forming infinite three-dimensional -Cd-S=C=N-Zn- networks , and are essentially linear at C and N, but bent at S. The structure exhib its a high non-linear optical property, and physical and chemical stability .