{[mu-N,N '-bis(salicylidene)-1,3-propane diaminato]copper(II)}dichloromercury(II)

Authors
Atakol, O Arici, C Tahir, MN Kenar, A Ulku, D
Citation
O. Atakol et al., {[mu-N,N '-bis(salicylidene)-1,3-propane diaminato]copper(II)}dichloromercury(II), ACT CRYST C, 55, 1999, pp. 1416-1418
Citations number
9
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
9
Pages
1416 - 1418
Database
ISI
SICI code
0108-2701(19990915)55:<1416:{'D>2.0.ZU;2-K
Abstract
The title compound, [CuHgCl2(C17H16N2O2)], is a hetero-dinuclear complex co ntaining Cu-II and Hg-II ions. The Cu-II centre has a distorted square-plan ar coordination involving two O and two N atoms from the imine-phenol ligan d, with Cu-O distances of 1.920 (3) kand 1.926 (2) Angstrom, and Cu-N dista nces of 1.966 (3) and 1.986 (4) Angstrom. The coordination around the Hg-II centre consists of two chloride ions at distances of 2.343 (1) and 2.325 ( 2) Angstrom, and two phenolic O atoms of the organic ligand at distances of 2.516(2) and 2.421 (3) Angstrom. The Cu ... Hg separation is 3.5301 (8) An gstrom.