Dimeric (pyrazole-N-2)(N-salicylidene-2,2-dimethylglycinato-O,N,O ')copper(II) pyrazole solvate

Authors
Citation
E. Hill et Sa. Warda, Dimeric (pyrazole-N-2)(N-salicylidene-2,2-dimethylglycinato-O,N,O ')copper(II) pyrazole solvate, ACT CRYST C, 55, 1999, pp. 1431-1434
Citations number
11
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
9
Pages
1431 - 1434
Database
ISI
SICI code
0108-2701(19990915)55:<1431:D('>2.0.ZU;2-Y
Abstract
In the title compound, bis(mu-N-salicylidene-2,2-dimethylglycinato)bis [(py razole)copper(II)] bis(pyrazole) solvate, [Cu-2(C11H11NO3)(2)(C3H4N2)(2)]. 2C(3)H(4)N(2), the Cu-II atom adopts a square-pyramidal copper(II) coordina tion with both a tridentate 2,2-dimethyl-N-salicylideneglycinate Schiff bas e dianion and a pyrazole ligand forming the basal plane. The apex of the py ramid is occupied by an O atom from an adjacent chelate molecule at a dista nce of 2.605 (2) Angstrom, building a centrosymmetric dimer. All copper pol yhedra belonging to one dimer are oriented parallel to each other, whereas the dimers are ordered antiferrodistortively.