1-N,2-O-carbonyl-3,5-O-isopropylidene-1-N-[(2R)-2-methyl-3-oxopentanoyl]-alpha-D-xylofuranosylamine

Citation
J. Kopf et al., 1-N,2-O-carbonyl-3,5-O-isopropylidene-1-N-[(2R)-2-methyl-3-oxopentanoyl]-alpha-D-xylofuranosylamine, ACT CRYST C, 55, 1999, pp. 1541-1542
Citations number
13
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
9
Pages
1541 - 1542
Database
ISI
SICI code
0108-2701(19990915)55:<1541:1>2.0.ZU;2-S
Abstract
The title compound, C15H21NO7, was synthesized as part of a study involving the testing of new carbohydrate-derived chiral auxiliaries. Its solid-stat e conformation and absolute configuration were determined. The R configurat ion for the chiral centre at C-22, created during the synthesis, was deduce d from knowledge of the absolute structure of the D-xylose moiety.